Have to agree about Yeoman Janice Rand being one of the sexier Trek women. On one of the boxed Trek sets there is a tiny interview with her from 2000 & she's in her original Trek duds. Scary but not as bad as you would think.
G-man gives a good argument for Captain Kirk but I had to go with Picard. He saved the universe a couple of times & I just can't see Kirk winning against the Borg. Who would he have slept with for starters?;)
I like all the Trek shows but picked Voyager as best Trek. The over all superior cast makes it the winner for me. It combined all the old elements & still kept things new by exploring a new ground.